全文获取类型
收费全文 | 368篇 |
免费 | 14篇 |
国内免费 | 3篇 |
专业分类
化学 | 178篇 |
晶体学 | 6篇 |
力学 | 26篇 |
数学 | 98篇 |
物理学 | 77篇 |
出版年
2023年 | 7篇 |
2022年 | 4篇 |
2021年 | 7篇 |
2020年 | 14篇 |
2019年 | 15篇 |
2018年 | 11篇 |
2017年 | 18篇 |
2016年 | 25篇 |
2015年 | 12篇 |
2014年 | 14篇 |
2013年 | 33篇 |
2012年 | 32篇 |
2011年 | 31篇 |
2010年 | 29篇 |
2009年 | 19篇 |
2008年 | 14篇 |
2007年 | 20篇 |
2006年 | 17篇 |
2005年 | 7篇 |
2004年 | 8篇 |
2003年 | 6篇 |
2002年 | 7篇 |
2001年 | 3篇 |
2000年 | 1篇 |
1999年 | 3篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1996年 | 4篇 |
1994年 | 2篇 |
1993年 | 5篇 |
1992年 | 1篇 |
1991年 | 3篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1975年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有385条查询结果,搜索用时 15 毫秒
21.
M. Mahmoudi M. A. Shokrgozar S. Bonakdar M. K. Moghadam S. Laurent 《Journal of the Iranian Chemical Society》2011,8(4):944-950
Superparamagnetic iron oxide nanoparticles (SPIONs) are being increasingly used in various biomedical processes such as hyperthermia, cell and protein separation, enhancing resolution of magnetic resonance imaging and drug delivery. Here, SPIONs were prepared by optimized co-precipitation of iron chlorides in basic medium and then coated with gold. Bare SPIONs and Aucoated SPIONs were characterized by TEM before incubation with fetal bovine serum for 0.5, 1, 2, 4, 8 and 24 h. After these interaction times, the mixture was deposed on a small column in a strong magnetic field (MACS?system). The SPIONs were retained; different washing fractions were collected and studied by UV-Vis spectroscopy and by 1D gel electrophoresis. The study revealed the presence of proteins in the washing solutions and confirmed the strong interaction of the protein with the SPIONs. 相似文献
22.
The present work is devoted to the experimental and numerical study ofthe interaction of a turbulent plane jet with a rectangular cavity.Several flow regimes have been found to occur: the non-oscillationregime, the stable oscillation regime and an unstable oscillationregime. The first two regimes have been particularly considered. Theexperimental study has been carried out using hot wire anemometry andsome visualisations. The numerical predictions based on statisticalmodelling have been made using on the one hand the standard k– model and on the other hand a two-scales split spectrum model. The structuralproperties of the flow have been described for the different situations.For the oscillatory regime, a parametrical study allowed to determinethe influence of the jet exit location and the Reynolds number on thefrequency of the jet flapping. The one point closures have been able topredict the oscillatory regime, and in particular the two-scales modelled to improved results because better account is taken of lag effectsin unsteady non-equilibrium situations. 相似文献
23.
24.
Different novel phthalazino[2,3‐b]phthalazine‐5,7,12,14‐tetraones were synthesized in a simple and environmentally benign method from the reaction of phthalic anhydrides with semicarbazide or thiosemicarbazide using montmorillonite K‐10 clay as solid heterogeneous acidic catalyst and microwaves under solvent‐free conditions in good yields and short reaction times. Products were characterized by the elemental analysis, IR, NMR, and mass spectrometry. 相似文献
25.
The successive approximation method was applied for the first time by N.I. Ioakimidis to solve practical cases of a Cauchy singular integral equation: the airfoil one. In this paper we study a more general case. We prove the convergence of the method in this general case. The proposed method has been tested for two kernels which are particularly important in practice. Finally, some numerical examples illustrate the accuracy of the method. 相似文献
26.
M. G. Mahmoudi 《Proceedings Mathematical Sciences》2010,120(5):535-561
Involutions of the Clifford algebra of a quadratic space induced by orthogonal symmetries are investigated. 相似文献
27.
Chian Wen Chan Anke Brems Shiva Mahmoudi Jan Baeyens Jonathan Seville David Parker Thomas Leadbeater Joseph Gargiuli 《Particuology》2010,8(6):623-630
Laboratory and industrial risers are equipped with exits of many different layouts, and numerous publications discuss the influence of riser exit geometry on local and overall solids hydrodynamics in the riser. The present paper reviews literature findings--mostly based upon indirect experimental techniques and often somewhat contradictory, Direct measurement of particle velocity and particle occupancy near and in the riser exit provide a better indication of the effect of riser exit geometry. Positron Emission Particle Tracking (PEPT) was used in this work for the first time to investigate the exit region of the riser, An abrupt or sharp exit causes particles to be knocked out of the gas flow, so forming a recirculation or reflux region in the upper part of the riser. This is much less pronounced with a curved or gradual exit. 相似文献
28.
Improved double-gate armchair silicene nanoribbon field-effect-transistor at large transport bandgap 下载免费PDF全文
The electrical characteristics of a double-gate armchair silicene nanoribbon field-effect-transistor(DG ASi NR FET)are thoroughly investigated by using a ballistic quantum transport model based on non-equilibrium Green's function(NEGF) approach self-consistently coupled with a three-dimensional(3D) Poisson equation. We evaluate the influence of variation in uniaxial tensile strain, ribbon temperature and oxide thickness on the on-off current ratio, subthreshold swing, transconductance and the delay time of a 12-nm-length ultranarrow ASi NR FET. A novel two-parameter strain magnitude and temperature-dependent model is presented for designing an optimized device possessing balanced amelioration of all the electrical parameters. We demonstrate that employing Hf O2 as the gate insulator can be a favorable choice and simultaneous use of it with proper combination of temperature and strain magnitude can achieve better device performance.Furthermore, a general model power(GMP) is derived which explicitly provides the electron effective mass as a function of the bandgap of a hydrogen passivated ASi NR under strain. 相似文献
29.
30.
The design, synthesis, and characterization of the 10 linear and bent acentric ligands 1 – 10 (tectons) based on the differentiation of two divergently disposed coordinating poles is reported. The nature of the two poles and their distance are varied by the use of different linear spacers. For these molecules, a monodentate coordinating site, i.e., a pyridine ring, and a tridentate coordinating site, i.e., a pyridine moiety bearing at the 2 and 6 positions either two thioether groups or two dimethylamino units (PySMe and PyN(Me2)2 type, resp.), a terpyridine, or a pyridine ring bearing two optically pure dihydrooxazole units, are combined. 相似文献